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Scholarly Interest Report
         
Douglas Natelson
Associate Professor
Associate Professor of Physics and Astronomy and Electrical and Computer Engineering
 
e-mail:natelson@rice.edu
 
  • Ph.D. Experimental condensed matter physics (1998) Stanford University
  • BSE Mechanical and Aerospace Engineering / Engineering-Physics (1993) Princeton University
 
Primary Department
   Department of Physics and Astronomy
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Department Affiliations
 
  • Center for Biological and Environmental Nanotechnology
  • Department of Electrical and Computer Engineering
  • Rice Quantum Institute
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    Websites
     Nanoscale Views
     PHYS533: Nanostructures and Nanotechnology I
     PHYS534: Nanostructures and Nanotechnology II
     Group homepage
     Natelson's Homepage
     
    Research Areas
     Experimental Condensed Matter Physics, nanotechnology, nanostructures, nanoelectronics, organic electronics, strongly correlated materials, plasmonics
     
    Research statement
     

    Doug Natelson is interested in nanoscale physics, in particular the electrical and magnetic properties of systems with characteristic dimensions approaching the single-nm scale. A variety of unusual phenomena arise in this size regime, and an understanding of the properties of matter on these scales may well have a profound impact on future technologies.


    To explicitly see the impact of quantum mechanics on the properties of matter (e.g. quantum interference contributions to electrical conduction) typically requires small systems (~ 1 micron, or 1/100 the diameter of a human hair) and low temperatures (often < 4.2 K, or -269 degrees Celcius). However, at the atomic size limit quantum effects can dominate even at room temperature. The transition from quantum to classical behavior is called "decoherence" or "dephasing". As systems approach the nanoscale the interplay between quantum effects, the "decohering" influence of the environment, electronic correlations like magnetism and superconductivity, and disorder lead to an impressively rich area of study.


    Techniques now exist for controllably fabricating structures with characteristic lengths below 10 nm, through both "top-down" methods (combining electron beam lithography, directional etching, and metal deposition) and "bottom-up" approaches (chemical fabrication, self-assembly). We can now examine "traditional" solid state systems at previously unexplored scales by making samples in this newly accessible regime. Further, we can utilize our skills to develop tools (e.g. sets of nm-spaced electrodes, sensitive nanomagnetometers) for studying novel materials such as fullerenes and other molecular and molecular-scale objects.


    Areas of interest include electronic, magnetic, and optical studies of atomic- and molecular-scale devices; nanostructure-based studies of strongly correlated materials, and organic semiconductors. Eventual technological relevance may be possible in areas such as molecular electronics and quantum information processing.


    In addition to learning a lot of neat physics, people in this research group will develop skills in micro- and nanofabrication, sensitive electrical measurements, various microscopy techniques, semiconductor physics, low temperature physics, and vacuum systems. Anyone interested in working in this group is encouraged to send email (natelson@rice.edu), and all those interested in this area in general are welcome to look at the reference materials for Doug's special topics course from Fall 2000, (PHYS600: Introduction to Nanoscale Science and Technology).

     
    Teaching Areas
     statistical physics, nanoscale physics, nanotechnology
     
    Selected Publications
     Articles
     

    D. Natelson, "Correlated electron systems: better than average", Nature Nano. 4, 406-407 (2009).

     
     

    D. Natelson, "Towards the ultimate transistor", Physics World 22, 27-31 (2009). Also re-published in abridged form in Compound Semiconductor magazine.

     
     Conference papers
     D. Natelson, B.H. Hamadani, J.W. Ciszek, D.A. Corley, and J.M. Tour "Contact effects in polymer field-effect transistors." Proceedings of the SPIE, 6336 (2006) : 63360M.
     
     Refereed Articles
     A. A. Fursina, R. G. S. Sofin, I. V. Shvets, and D. Natelson "Interplay of bulk and interface effects in the electric field driven transition in magnetite." Submitted
     
     

    A. A. Fursina, R. G. S. Sofin, I. V. Shvets, and D. Natelson "The origin of hysteresis in resistive switching in magnetite is Joule heating", Phys. Rev. B 79, 245131 (2009)

     
     

    A. Sinitskii, A. A. Fursina, D. Kosynkin, A. Higginbotham, D. Natelson, and J. M. Tour, "Electronic transport in monolayer graphene nanoribbons produced by chemical unzipping of carbon nanotubes", Appl. Phys. Lett., in press (2009).

     
     G. D. Scott and D. Natelson "Kondo resonances in molecular devices." Submitted
     
     G. D. Scott, J. J. Palacios, and D. Natelson "Anomalous transport and possible phase transition in Pd nanojunctions." Submitted
     
     

    G. D. Scott, Z. K. Keane, J. W. Ciszek, J. M. Tour, and D. Natelson. "Universal scaling of nonequilibrium transport in the Kondo regime of single molecule devices", Phys. Rev. B 79, 165413 (2009)

     
     

    J. Yao, J. Zhong, L. Zhong, D. Natelson, and J. M. Tour, "Two-terminal nonvolatile memories based on single-walled carbon nanotubes", ACS Nano, in press (2009).

     
     

    M. R. Calvo, J. Fernandez-Rossier, J. J. Palacios, D. Jacob, D. Natelson, and C. Untiedt. "The Kondo Effect in ferromagnetic atomic contacts", Nature 458, 1150-1153 (2009).

     
     P. J. Wheeler, J. N. Russom, K. Evans, N. S. King, and D. Natelson "Shot noise suppression at room temperature in atomic-scale Au contacts." Submitted
     
     A. Fursina, S. Lee, R. G. S. Sofin, I. V. Shvets, and D. Natelson, "Nanogaps with very large aspect ratios for electrical measurements", Appl. Phys. Lett. 92, 113102 (2008).
     
     D. R. Ward, G. D. Scott, Z. K. Keane, N. J. Halas, and D. Natelson, "Electronic and optical properties of electromigrated molecular junctions", J. Phys: Condens. Matter 20, 374118 (2008).
     
     D. R. Ward, N. J. Halas, J. W. Ciszek, J. M. Tour, Y. Wu, P. Nordlander, and D. Natelson, "Simultaneous measurements of electronic conduction and Raman response in molecular junctions", Nano Lett. 8, 919-924 (2008).
     
     D. R. Ward, N. J. Halas, and D. Natelson. "Localized heating in nanoscale Pt constrictions measured using blackbody radiation emission", Appl. Phys. Lett. 93, 213108 (2008).
     
     J. H. Worne, R. Giridharagopal, K. F. Kelly, and D. Natelson. "Interfacial charge transfer in nanoscale polymer transistors", Nano Research 1, 341-350 (2008).
     
     J. Yao, L. Zhong, D. Natelson, and J. M. Tour "Etching-dependent reproducible memory switching in vertical SiO2 structures", Appl. Phys. Lett. 93, 253101 (2008).
     
     S. Lee, A. Fursina, J. T. Mayo, C. T. Yavuz, V. L. Colvin, R. G. S. Sofin, I. V. Shvets, and D. Natelson, "Electrically-driven phase transition in magnetite nanostructures", Nature Materials, 7, 130-133 (2008)
     
     A. Trionfi, S. Lee, and D. Natelson, “Time-dependent universal conductance fluctuations in mesoscopic Au wires: implications”, Phys. Rev. B 75, 104202 (2007).
     
     D.R. Ward, N.K. Grady, C.S. Levin, N.J. Halas, Y. Wu, P. Nordlander, and D. Natelson, “Electromigrated nanoscale gaps for surface-enhanced Raman spectroscopy ”, Nano Lett. 7, 1396-1400 (2007).
     
     S. Lee, A. Trionfi, T. Schallenberg, H. Munekata, and D. Natelson, “Quantum coherence in ferromagnetic semiconductors: time-dependent universal conductance fluctuations and magnetofingerprint”, Appl. Phys. Lett. 90, 032105 (2007).
     
     B.H. Hamadani, D.A. Corley, J.W. Ciszek, J.M. Tour, and D. Natelson "Controlling charge injection in organic field-effect transistors using self-assembled monolayers." Nano Lett., 6 (2006) : 1303-1306.
     
     C.H. Ahn, A. Bhattacharya, M. Di Ventra, J.N. Eckstein, C. Daniel Frisbie, M.E. Gershenson, A.M. Goldman, I.H. Inoue, J. Mannhart, A.J. Millis, A.F. Morpurgo, D. Natelson, and J.-M. Triscone "Electrostatic modification of novel materials." Rev. Mod. Phys., 78 (2006) : 1185-1212.
     
     C.T. Yavuz, J.T. Mayo, W.W. Wu, A. Prakash, J.C. Falkner, S. Yean, L. Cong, H.J. Shipley, A. Kan, M. Tomson, D. Natelson, and V.L. Colvin "Low-field magnetic separation of monodisperse Fe3O4 nanocrystals." Science, 314 (2006) : 964-967.
     
     D. Natelson, L.H. Yu, J.W. Ciszek, Z.K. Keane, and J.M. Tour "Single-molecule transistors: electron transfer in the solid state." Chemical Physics, 324 (2006) : 267-275.
     
     J.W. Ciszek, Z.K. Keane, L. Cheng, M.P. Stewart, L.H. Yu, D. Natelson, and J.M. Tour "Neutral complexes of first row transition metals bearing unbound thiocyanates and their assembly on metallic surfaces." J. Am. Chem. Soc., 128 (2006) : 3179-3189.
     
     Z.K. Keane, J.W. Ciszek, J.M. Tour, and D. Natelson "Three-terminal devices to examine single-molecule conductance switching." Nano Lett., 6 (2006) : 1518-1521.
     
     Z.K. Keane, L.H. Yu, and D. Natelson "Magnetoresistance of atomic-scale electromigrated nickel nanocontacts." Applied Physics Letters, 88 (2006) : 062514.
     
     A. Trionfi, S. Lee, and D. Natelson "Time-dependent universal conductance fluctuations and coherence in AuPd and Ag." Physical Review B, 72 (2005) : 035407.
     
     B. Hamadani, D. Natelson "Nonlinear charge injection in organic field-effect transistors." Journal of Applied Physics, 97 (2005) : 064508.
     
     B.H. Hamadani, D. Natelson "Extracting contact effects in organic field-effect transistors." Proceedings of the IEEE, Special Issue on Flexible Electronics Technology, 93 (2005) : 1306-1311.
     
     B.H. Hamadani, Natelson, D. "Gated nonlinear transport in organic polymer field effect transistors." Journal of Applied Physics, 95 (2004) : 1227-1232.
     
     L.H. Yu, Z.K. Keane, J.W. Ciszek, L. Cheng, J.M. Tour, T. Baruah, M.R. Pederson, and D. Natelson "Strong Kondo physics and anomalous gate dependence in single-molecule transistors." Physical Review Letters, 95 (2005) : 256803.
     
     L.H. Yu, Z.K. Keane, J.W. Ciszek, L. Cheng, M.P. Stewart, J.M. Tour, and D. Natelson "Inelastic electron tunneling via molecular vibrations in single-molecule transistors." Physical Review Letters, 93 (2004) : 266802.
     
     S. Kirchner, L. Zhu, Q. Si, and D. Natelson "Quantum critical Kondo effect in a quantum dot coupled to ferromagnetic leads." Proceedings of the National Academy of Sciences of the United States, 102 (2005) : 18824-18829.
     
     B.H. Hamadani and D. Natelson "Temperature-dependent contact resistances in high quality polymer field-effect transistors." Appl. Phys. Lett., 84 (2004) : 443-445.
     
     L.H. Yu and D. Natelson "Kondo physics in C60 single-molecule transistors." Nano Letters, 4(1) (2004) : 79-84.
     
     Refereed Conference Papers
     D. Natelson, L. H. Yu, Z. K. Keane, J. W. Ciszek, and J. M. Tour, "Anomalous gate dependence of the Kondo effect in single-molecule transistors", Physica B, 403 1526-1528 (2008).
     
     A. Trionfi, S. Lee, and D. Natelson "Time dependent universal conductance fluctuations in AuPd, Ag, and Au wires." AIP Conf. Proc., 850 (2006) : 1411-1412.
     
     D. Natelson, L.H. Yu, Z.K. Keane, J.W. Ciszek, L. Cheng, and J.M. Tour "Kondo physics in single-molecule transistors." AIP Conf. Proc., 850 (2006) : 1365-1366.
     
    Presentations
     Invited Talks
     "Atomic and molecular scale devices: beyond DC electronic transport." Physics and Astronomy Colloquium, Rice University, Houston, TX. (9/2009)
     
     "Correlations in single-molecule transistors and other nanoscale junctions." Hangzhou Workshop on Quantum Matter, Zhejiang University, Hangzhou, China. (10/2009)
     
     "Nanostructures for fun and (intellectual) profit." Carleton College. (4/2009)
     
     "Nanostructures to examine transport, dissipation, and correlations." Center for Nanoscale Materials, Argonne National Lab. (3/2009)
     
     "Simultaneous electronic transport and Raman spectroscopy in single-molecule devices." National Nanotechnology Initiative Workshop on Nanotechnology Enabled Sensing, Arlington, VA. (5/2009)
     
     "Simultaneous electronic transport and Raman spectroscopy in single-molecule devices." International CECAM workshop on Quantum Transport at the Molecular Scale, Bremen, Germany. (9/2009)
     
     "Simultaneous electronic transport and Raman spectroscopy in single-molecule devices." American Physical Society March Meeting, Pittsburgh, PA. (3/2009)
     
     Seminar Speaker
     "Atomic and molecular scale devices: beyond DC electronic transport." Center for Nanophysics and Advanced Materials colloquium, University of Maryland, College Park, MD. (12/2009)
     
     "Atomic and molecular scale devices: beyond DC electronic transport." Michigan State University Department of Physics and Astronomy, East Lansing, MI. (11/2009)
     
    Supervised Theses & Dissertations
     Lam H. Yu, Ph D Transport in Single Molecule Transistors. (2005) (Thesis or Dissertation Director)

     Behrang H. Hamadani, PhD Electronic charge injection and transport in organic field-effect transistors. (2006) (Thesis or Dissertation Director)

     Aaron J. Trionfi, PhD Electronic phase coherence in mesoscopic normal metal wires. (2006) (Thesis or Dissertation Director)

     Sungbae Lee, Ph. D. Electron Transport in Ferromagnetic Nanostructures. (2007) (Thesis or Dissertation Director)

     Zachary K. Keane, Ph. D Transport Phenomena in Molecular-Scale Devices. (2009) (Thesis or Dissertation Director)

     Jeffrey Howard Worne, MSEE Interfacial charge transfer in nanoscale polymer transistors. (2009) (Thesis or Dissertation Director)

    Awards, Prizes, & Fellowships
     Alfred P. Sloan Foundation Research Fellowship, Alfred P. Sloan Foundation (2004-2006)

     David and Lucille Packard Foundation Fellowship, David and Lucille Packard Foundation (2003-2008)

     CAREER grant, National Science Foundatioon (2004-2009)

     Outstanding Faculty Associate, Wiess College, Rice University (5/20/2002)

     Research Innovation Award, Research Corporation (5/1/2002)